$\{a\} \neq \{\{a\}\}$
$\{a\}$ is the set whose only element is the a (and no others). $\{\{a\}\}$ is the set whose only element is the set $\{a\}$.
Does this mean the 'element a' is not equal to 'set $\{a\}$'?
$\endgroup$ 23 Answers
$\begingroup$Even though people sometimes get sloppy about it, $a$ and $\{a\}$ are not the same object. $a$ is the only element of the set $\{a\}$.
$\endgroup$ $\begingroup$They are not equal.
Intuitively, $\{a\}$ means a set which contains an element $a$; while $\{\{a\}\}$ means a set that contains a set $\{a\}$ as its element.
From ZFC axiom: Every non-empty set $x$ contains a member $y$ such that $x$ and $y$ are disjoint sets.
$\endgroup$ $\begingroup$In general: $$\{x\}=\{y\}\iff x=y$$
Then we can conclude that also:$$\{x\}\neq\{y\}\iff x\neq y$$
Applying that in your case we find that the statement $\{a\}\neq\{\{a\}\}$ is the same statement as $a\neq\{a\}$.
Sidenote:
If also the axiom of regularity is accepted then this statement is true for every $a$.
This because on base of that axiom it can be proved that $a\notin a$ is true for every $a$ while $a=\{a\}$ implies that $a\in a$.
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